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1．Explosives of Divisions 1.1, 1.2, 1.3, 1.4 2． Self reactive substances and mixtures, Types A,B 3． Organic peroxides, Types A,B |
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1． Flammable gases, category 1 2． Flammable aerosols, categories 1,2 3． Flammable liquids, categories 1,2,3 4． Flammable solids, categories 1,2 5． Self-reactive substances and mixtures, Types B,C,D,E,F 6． Pyrophoric liquids, category 1 7． Pyrophoric solids, category 1 8． Self-heating substances and mixtures, categories 1,2 9． Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3 10． Organic peroxides, Types B,C,D,E,F |
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1．
Oxidizing gases, category 1 2． Oxidizing liquids, categories 1,2,3 |
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Gases under pressure:
1. Compressed gases 2. Liquefied gases 3. Refrigerated liquefied gases 4. Dissolved gases |
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1． Corrosive to metals, category 1 2． Skin corrosion, categories 1A,1B,1C 3． Serious eye damage, category 1 |
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Acute toxicity (oral, dermal, inhalation), categories 1,2,3 |
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1． Acute toxicity (oral, dermal, inhalation), category 4 2． Skin irritation, category 2 3． Eye irritation, category 2 4． Skin sensitisation, category 1 5． Specific Target Organ Toxicity – Single exposure, category 3 |
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1．
Respiratory sensitization, category 1 2． Germ cell mutagenicity, categories 1A,1B,2 3． Carcinogenicity, categories 1A,1B,2 4． Reproductive toxicity, categories 1A,1B,2 5． Specific Target Organ Toxicity – Single exposure, categories 1,2 6． Specific Target Organ Toxicity – Repeated exposure, categories 1,2 7.Aspiration Hazard, category 1 |
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Hazardous to the aquatic environment 1. Acute hazard, category1 2. Chronic hazard, categories 1,2 |
| Safety Phrases | Description |
| S1 | Keep locked up. |
| S1/2 | Keep locked up and out of reach of children. |
| S2 | Keep out of reach of children. |
| S3 | Keep in a cool place. |
| S3/14 | Keep in a cool place away from ... (incompatible materials to be indicated by the manufacturer). |
| S3/7 | Keep container tightly closed in a cool place. |
| S3/7/9 | Keep container tightly closed in a cool, well-ventilated place. |
| S3/9 | Keep in a cool, well-ventilated place. |
| S3/9/14 | Keep in a cool, well-ventilated place away from ... (incompatible material to be indicated by the manufacturer) |
| S3/9/14/49 | Keep only in the original container in a cool, well-ventilated place away from ... |
| S3/9/49 | Keep only in the original container in a cool, well-ventilated place. |
| S4 | Keep away from living quarters. |
| S5 | Keep contents under ... (appropriate liquid to be specified by the manufacturer). |
| S6 | Keep under ... (inert gas to be specified by the manufacturer). |
| S7 | Keep container tightly closed. |
| S7/47 | Keep container tightly closed and at a temperature not exceeding ...(to be specified by the manufacturer) |
| S7/8 | Keep container tightly closed and dry. |
| S7/9 | Keep container tightly closed and in a well-ventilated place |
| S8 | Keep container dry. |
| S9 | Keep container in a well-ventilated place. |
| S12 | Do not keep the container sealed. |
| S13 | Keep away from food, drink and animal feeding stuffs. |
| S14 | Keep away from ... (incompatible materials to be indicated by the manufacturer). |
| S15 | Keep away from heat. |
| S16 | Keep away from sources of ignition - No smoking. |
| S17 | Keep away from combustible material. |
| S18 | Handle and open container with care. |
| S20 | When using do not eat or drink. |
| S20/21 | When using do not eat, drink or smoke. |
| S21 | When using do not smoke. |
| S22 | Do not breathe dust. |
| S23 | Do not breathe gas/fumes/vapour/spray. |
| S24 | Avoid contact with skin. |
| S24/25 | Avoid contact with skin and eyes。 |
| S25 | Avoid contact with eyes. |
| S26 | In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
| S27 | Take off immediately all contaminated clothing. |
| S28 | After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer). |
| S29 | Do not empty into drains. |
| S29/56 | Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point. |
| S30 | Never add water to this product. |
| S31 | Keep away from explosive materials. |
| S33 | Take precautionary measures against static discharges. |
| S34 | Avoid shock and friction. |
| S35 | This material and its container must be disposed of in a safe way. |
| S36 | Wear suitable protective clothing. |
| S36/37 | Wear suitable protective clothing and gloves. |
| S36/37/39 | Wear suitable protective clothing, gloves and eye/face protection. |
| S36/39 | Wear suitable protective clothing and eye/face protection. |
| S37 | Wear suitable gloves. |
| S37/39 | Wear suitable gloves and eye/face protection. |
| S38 | In case of insufficient ventilation, wear suitable respiratory equipment. |
| S39 | Wear eye/face protection. |
| S40 | To clean the floor and all objects contaminated by this material, use ... (to be specified by the manufacturer). |
| S41 | In case of fire and/or explosion do not breathe fumes. |
| S42 | During fumigation/spraying wear suitable respiratory equipment. |
| S43 | In case of fire, use ... (if water increases the risk, add - never use water). |
| S44 | If you feel unwell, seek medical advice (show the label where possible). |
| S45 | In case of accident or if you feel unwell, seek medical advice immediately (show the lable where possible). |
| S46 | If swallowed, seek medical advice immediately and show this container or label. |
| S47 | Keep at temperature not exceeding ... degr. C (to be specified by the manufacturer). |
| S47/49 | Keep only in the original container at temperature not exceeding ... degr. C (to be specified by the manufacturer) |
| S48 | Keep wetted with ... (appropriate material to be specified by the manufacturer). |
| S49 | Keep only in the original container. |
| S50 | Do not mix with ... (to be specified by the manufacturer). |
| S51 | Use only in well-ventilated areas. |
| S52 | Not recommended for interior use on large surface areas. |
| S53 | Avoid exposure - obtain special instructions before use. |
| S54 | Obtain the consent of pollution control authorities before discharging to wastewater treatment plants. |
| S55 | Treat using the best available techniques before discharge into drains or the aquatic environment. |
| S56 | Dispose of this material and its container at hazardous or special waste collection point. |
| S57 | Use appropriate containment to avoid environmental contamination. |
| S58 | To be disposed of as hazardous waste. |
| S59 | Refer to manufacturer/supplier for information on recovery/recycling. |
| S60 | This material and/or its container must be disposed of as hazardous waste. |
| S61 | Avoid release to the environment. Refer to special instructions/Safety data sheets. |
| S62 | If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. |
| S14A | Keep away from acids, reducing agents and polymerisation catalysts. |
| S14B | Keep away from organic material and metal powders. |
| S14C | Keep away from water, acids and alkali. |
| S28A | After contact with skin, wash immediately with plenty of water. |
| S28B | After contact with skin, wash immediately with plenty of water and soap. |
| S28C | After contact with skin, wash immediately with a sodium borate solution. |
| S43A | In case of fire, use dry chemical. (never use water) |
| S43B | In case of fire, use fire-fighting equipment on basis of sodium chloride or sodium bicarbonate (never use water). |
| S43C | In case of fire use limestone powder, sodium chloride or dry sand (never use water). |
| S43D | In case of fire, use sodium carbonate or dry sand (never use water). |
| S43E | In case of fire, use dry sand (never use water). |
| S43F | Use water in case of Fire |
| S47A | Keep at temperature not exceeding 65 degr. C. |
| S50A | Do not mix with acids. |
| S5A | Keep contents under oil. |
| S5B | Keep contents under liquids which are oxygen-free, e.g. kerosene, toluene, etc. |
| S6A | Keep under nitrogen. |